| Academic Year |
2024Year |
School/Graduate School |
School of Engineering |
| Lecture Code |
K7158030 |
Subject Classification |
Specialized Education |
| Subject Name |
錯体化学 |
Subject Name
（Katakana） |
サクタイカガク |
Subject Name in
English |
Organometallic Chemistry |
| Instructor |
OSAKA ITARU |
Instructor
(Katakana) |
オサカ イタル |
| Campus |
Higashi-Hiroshima |
Semester/Term |
3rd-Year, First Semester, 1Term |
| Days, Periods, and Classrooms |
(1T) Mon1-2,Thur3-4：ENG 117 |
| Lesson Style |
Lecture |
Lesson Style
(More Details) |
|
| Lecture |
| Credits |
2.0 |
Class Hours/Week |
|
Language of Instruction |
J
:
Japanese |
| Course Level |
3
:
Undergraduate High-Intermediate
|
| Course Area（Area） |
25
:
Science and Technology |
| Course Area（Discipline） |
07
:
Chemistry |
| Eligible Students |
third-year student |
| Keywords |
organometallics, organometallic catalysis, organic synthesis |
| Special Subject for Teacher Education |
|
Special Subject |
|
Class Status
within Educational
Program
(Applicable only to targeted subjects for undergraduate students) | |
|---|
Criterion referenced
Evaluation
(Applicable only to targeted subjects for undergraduate students) | Program of Applied Chemistry
（Knowledge and Understanding）
・Wide range of basic knowledge on liberal arts and specialized education, and professional basic knowledge on chemistry.
・Advanced technical knowledge of applied chemistry.
・The conception ability based on logical thinking supported by basic and technical knowledge. |
|---|
Class Objectives
/Class Outline |
Organometallic chemistry is a very important area in organic synthesis because many of the useful organic reactions such as cross-coupling reactions utilize organometallic complexes as the catalysts. By the end of this class you should have an appreciation of:
(1) Fundamentals of organometallic complexes, such as counting electrons, formal oxidation number, metal-ligand bondings and coordinations
(2) Structures, properties, and theories of organometallic complexes
(3) Fundamentals of organometallic catalyzed reactions |
| Class Schedule |
lesson1: Basics of Orgametallic Chemisry
lesson2: Counting electrons -EAN rule, 18-electron rule
lesson3: Formal oxidation number
lesson4: Metal-ligand bondings and coordinations
lesson5: Crystal field theory
lesson6: Ligand field theory
lesson7: Carbonyl complex, Olefin complex
lesson8: Phosphine complex, Carbene complex
lesson9: Oxidative addition
lesson10: Reductive elimination
lesson11: Insertion and elimination reactions
lesson12: Metathesis reactions
lesson13: Polymerization of olefins and acetylenes
lesson14: Transition-metal catalyzed cross-coupling reactions
lesson15: Synthesis of π-conjugated polymers
term-end examination |
Text/Reference
Books,etc. |
"Yuki kinzoku kagaku" H. Nakazawa, K. Osakada Eds. Sankyo Shuppan |
PC or AV used in
Class,etc. |
|
| (More Details) |
text book |
| Learning techniques to be incorporated |
|
Suggestions on
Preparation and
Review |
Text books for "Physical Chemistry" and "Inorganic Chemistry" are useful for theoretical subject. |
| Requirements |
|
| Grading Method |
All points are determined by term-end examination. |
| Practical Experience |
|
| Summary of Practical Experience and Class Contents based on it |
|
| Message |
|
| Other |
|
Please fill in the class improvement questionnaire which is carried out on all classes.
Instructors will reflect on your feedback and utilize the information for improving their teaching. |