| Academic Year |
2024Year |
School/Graduate School |
School of Science |
| Lecture Code |
HJ340000 |
Subject Classification |
Specialized Education |
| Subject Name |
構造有機化学 |
Subject Name
（Katakana） |
コウゾウユウキカガク |
Subject Name in
English |
Structural Organic Chemistry |
| Instructor |
HAINO TAKEHARU |
Instructor
(Katakana) |
ハイノ タケハル |
| Campus |
Higashi-Hiroshima |
Semester/Term |
3rd-Year, First Semester, 1Term |
| Days, Periods, and Classrooms |
(1T) Tues3-4,Fri3-4：SCI E209 |
| Lesson Style |
Lecture |
Lesson Style
(More Details) |
|
| ppt |
| Credits |
2.0 |
Class Hours/Week |
|
Language of Instruction |
J
:
Japanese |
| Course Level |
3
:
Undergraduate High-Intermediate
|
| Course Area（Area） |
25
:
Science and Technology |
| Course Area（Discipline） |
07
:
Chemistry |
| Eligible Students |
junior |
| Keywords |
conformation, stereochemistry, chirality, stereoelectronic effect, supramolecular chemistry |
| Special Subject for Teacher Education |
|
Special Subject |
|
Class Status
within Educational
Program
(Applicable only to targeted subjects for undergraduate students) | |
|---|
Criterion referenced
Evaluation
(Applicable only to targeted subjects for undergraduate students) | Chemistry
（Knowledge and Understanding）
・Understanding and learning advanced expertise in several chemical and interdisciplinary areas. |
|---|
Class Objectives
/Class Outline |
Detailed understanding for stereochemistry of organic compounds, conformational characteristics, stereo electronic effect of organic reactions, and intermolecular association of supramolecular complexes |
| Class Schedule |
lesson1 introductory talk
lesson2 deals with stereo isomers including enantiomer, rotamer, and conformer. Symmetry and optical property of a molecule are described. Cahn-Ingold-Prelog priority rules are illustrated.
lesson3 deals with axial chirality, planar chirality, and helicity of a molecule. Optical resolution of racemic mixtures, and racemic compounds are described.
lesson4 deals with optical resolution.
lesson5 deals with asymmetric induction and transition state model.
lesson6 deals with asymmetric synthesis.
lesson7 deals with conformational characteristics of acyclic alkanes.
lesson8 deals with conformational characteristics of cyclic alkanes. A-values are described.
lesson9 deals with A-values.
lesson10 deals with conformational characteristics of a molecule with unsaturated bonds.
lesson11 deals with stereoelectronic effect.
lesson12 deals with supramolecular chemistry.
lesson13 deals with weak supramolecular interactions.
lesson14 deals with host-guest complexes formed via weak non covalent interactions.
lesson15 deals with host-guest complexes formed via uncommon non covalent interactions.
examination |
Text/Reference
Books,etc. |
Modern Organic Synthesis Lecture Note by Dale L. Boger.
Stereoelectronic effects by A. J. Kirby |
PC or AV used in
Class,etc. |
|
| (More Details) |
Digital information will be supplied. I will inform you how to download it. |
| Learning techniques to be incorporated |
|
Suggestions on
Preparation and
Review |
I'd recommend you to buy molecular models that help you to work out how each element is placed in a molecule. |
| Requirements |
|
| Grading Method |
A score of your examination. |
| Practical Experience |
|
| Summary of Practical Experience and Class Contents based on it |
|
| Message |
Purchasing a handy molecular model is recommended for this lecture. |
| Other |
|
Please fill in the class improvement questionnaire which is carried out on all classes.
Instructors will reflect on your feedback and utilize the information for improving their teaching. |