Hiroshima University Syllabus

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Academic Year 2023Year School/Graduate School School of Science
Lecture Code HJ340000 Subject Classification Specialized Education
Subject Name 構造有機化学
Subject Name
Subject Name in
Structural Organic Chemistry
ハイノ タケハル
Campus Higashi-Hiroshima Semester/Term 3rd-Year,  First Semester,  1Term
Days, Periods, and Classrooms (1T) Tues3-4,Fri3-4:SCI E209
Lesson Style Lecture Lesson Style
(More Details)
Credits 2.0 Class Hours/Week   Language of Instruction J : Japanese
Course Level 3 : Undergraduate High-Intermediate
Course Area(Area) 25 : Science and Technology
Course Area(Discipline) 07 : Chemistry
Eligible Students junior
Keywords conformation, stereochemistry, chirality, stereoelectronic effect, supramolecular chemistry 
Special Subject for Teacher Education   Special Subject  
Class Status
within Educational
(Applicable only to targeted subjects for undergraduate students)
Criterion referenced
(Applicable only to targeted subjects for undergraduate students)
(Knowledge and Understanding)
・Understanding and learning advanced expertise in several chemical and interdisciplinary areas. 
Class Objectives
/Class Outline
Detailed understanding for stereochemistry of organic compounds, conformational characteristics, stereo electronic effect of organic reactions, and intermolecular association of supramolecular complexes 
Class Schedule lesson1 introductory talk
lesson2 deals with stereo isomers including enantiomer, rotamer, and conformer. Symmetry and optical property of a molecule are described. Cahn-Ingold-Prelog priority rules are illustrated.
lesson3 deals with axial chirality, planar chirality, and helicity of a molecule. Optical resolution of racemic mixtures, and racemic compounds are described.  
lesson4 deals with optical resolution.
lesson5 deals with asymmetric induction and transition state model.
lesson6 deals with asymmetric synthesis.
lesson7 deals with conformational characteristics of acyclic alkanes.
lesson8 deals with conformational characteristics of cyclic alkanes. A-values are described.
lesson9 deals with A-values.
lesson10 deals with conformational characteristics of a molecule with unsaturated bonds.
lesson11 deals with stereoelectronic effect.
lesson12 deals with supramolecular chemistry.
lesson13 deals with weak supramolecular interactions.
lesson14 deals with host-guest complexes formed via weak non covalent interactions.
lesson15 deals with host-guest complexes formed via uncommon non covalent interactions.

Modern Organic Synthesis Lecture Note by Dale L. Boger.
Stereoelectronic effects by A. J. Kirby 
PC or AV used in
(More Details) Digital information will be supplied. I will inform you how to download it. 
Learning techniques to be incorporated  
Suggestions on
Preparation and
I'd recommend you to buy molecular models that help you to work out how each element is placed in a molecule. 
Grading Method A score of your examination. 
Practical Experience  
Summary of Practical Experience and Class Contents based on it  
Message Purchasing a handy molecular model is recommended for this lecture. 
Please fill in the class improvement questionnaire which is carried out on all classes.
Instructors will reflect on your feedback and utilize the information for improving their teaching. 
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